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Advances in Transition-Metal Mediated Heterocyclic Synthesis

Advances in Transition-Metal Mediated Heterocyclic Synthesis
  • Author : Daniel Sole,Israel Fernandez
  • Publisher :Unknown
  • Release Date :2018-05-17
  • Total pages :366
  • ISBN : 9780128116524
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Summary : Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. Helpfully organized by transformation type to stimulate the search for new synthetic processes Completely illustrated and written by global experts Includes thoughtfully selected strategies chosen by the editors to exemplify the state-of-the-art of the subject, including transition-metal reactions involving unsaturated systems, organopalladium chemistry, and metal-catalyzed C-H activation

Transition-Metal-Mediated Aromatic Ring Construction

Transition-Metal-Mediated Aromatic Ring Construction
  • Author : Ken Tanaka
  • Publisher :Unknown
  • Release Date :2013-07-09
  • Total pages :830
  • ISBN : 9781118629994
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Summary : State-of-the-science methods, synthetic routes, andstrategies to construct aromatic rings The development of new reactions for the synthesis of aromaticcompounds is a highly active research area in organic synthesis,providing new functional organic materials, functional reagents,and biologically active compounds. Recently, significant advancesin transition-metal-mediated reactions have enabled the efficientand practical construction of new aromatic rings with usefulproperties and applications. This book draws together and reviewsall the latest discoveries and methods in transition-metal-mediatedreactions, offering readers promising new routes to design andconstruct complex aromatic compounds. Integrating metal catalysis with aromatic compound synthesis,Transition-Metal-Mediated Aromatic Ring Construction offersa practical guide to the methods, synthetic routes, and strategiesfor constructing aromatic compounds. The book's five partsexamine: [2+2+2], [2+2+1], and related cycloaddition reactions [4+2], [3+2], and related cycloaddition reactions Electrocyclization reactions Coupling and addition reactions Other important transformations, including methathesisreactions and skeletal rearrangement reactions Edited by Ken Tanaka, an internationally recognized expert inthe field of transition-metal catalysis, the book features authorswho are leading pioneers and researchers in synthetic reactions.Their contributions reflect a thorough review and analysis of theliterature as well as their own firsthand laboratory experiencedeveloping new aromatic compounds. All chapters end with a summary and outlook, setting forth newavenues of research and forecasting new discoveries. There are alsoreferences at the end of each chapter, guiding readers to importantoriginal research reports and reviews. In summary, Transition-Metal-Mediated Aromatic RingConstruction offers synthetic chemists a promising new avenuefor the development of important new aromatic compounds with abroad range of applications.

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2020-04-24
  • Total pages :492
  • ISBN : 9780128211724
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Summary : Advances in Heterocyclic Chemistry is the definitive series in the field - one of great importance to organic chemists, polymer chemists, and many biological scientists. Because biology and organic chemistry increasingly intersect, the associated nomenclature also is being used more frequently in explanations. Written by established authorities in the field from around the world, this comprehensive review combines descriptive synthetic chemistry and mechanistic insight to yield an understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds. Considered the definitive serial in the field of heterocyclic chemistry Serves as the go-to reference for organic chemists, polymer chemists and many biological scientists Provides the latest comprehensive reviews written by established authorities in the field Combines descriptive synthetic chemistry and mechanistic insight to enhance understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds

Transition Metal Catalysed Reactions

Transition Metal Catalysed Reactions
  • Author : International Union of Pure and Applied Chemistry
  • Publisher :Unknown
  • Release Date :1999
  • Total pages :497
  • ISBN : UOM:39015050032583
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Summary :

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis
  • Author : Catherine S.J. Cazin
  • Publisher :Unknown
  • Release Date :2010-10-04
  • Total pages :340
  • ISBN : 9048128668
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Summary : N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book. Included in this book: Historical aspects of NHCs Synthetic pathways to NHC precursors, free NHCs and complexes Methods of characterisation of NHCs and related complexes Electronic properties of NHCs Steric properties of NHCs and models for their description NHCs for metathesis and cross-coupling reactions NHCs as organocatalysts NHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, ... Decomposition of NHC-containing catalysts Industrial applications involving NHC-containing catalysts N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.

Annual Reports on the Progress of Chemistry

Annual Reports on the Progress of Chemistry
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2007
  • Total pages :229
  • ISBN : PSU:000060864437
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Summary :

Catalyst Components for Coupling Reactions

Catalyst Components for Coupling Reactions
  • Author : Gary A. Molander
  • Publisher :Unknown
  • Release Date :1999
  • Total pages :676
  • ISBN : STANFORD:36105210544453
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Summary : The long awaited Handbook for all synthetic chemists working on coupling reactions, compiling all major catalyst components in use in the area. Consists of a compilation of articles taken from the EROS database, with the inclusion of about 20 newly commissioned catalysts/pre-catalysts/ligands that have made an impact in this area of synthetic organic chemistry. Includes catalyst systems used in Heck, Kumada-Tamao-Corriu, Suzuki-Miyaura, Hiyama-Hatanaka, Negishi, Migita-Kosugi-Stille, Buchwald-Hartwig, and Tsuji-Trost coupling reactions.

Boron Science

Boron Science
  • Author : Narayan S. Hosmane
  • Publisher :Unknown
  • Release Date :2016-04-19
  • Total pages :878
  • ISBN : 9781439826638
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Summary : Boron has made a significant impact in our lives through its quiet use in fertilizers, fungicides, soaps, detergents, and heat-resistant glassware. Boron Science: New Technologies and Applications addresses the applications of boron in chemistry, industry, medicine, and pharmacology by explaining its role in problems such as catalysis and hydroboration as well as its use in superconductors, materials, magnetic/nonmagnetic nanoparticles, and medical applications including cancer therapy. Illustrating the practical versatility of boron, the 29 chapters are divided into seven major sections: Boron for Living: Medicine Boron for Living: Health and Nutrition Boron for Living: Radioisotope Boron for Living: Boron Neutron Capture Therapy Boron for Electronics: Optoelectronics Boron for Energy: Energy Storage, Space, and Other Applications Boron for Chemistry and Catalysis: Catalysis and Organic Transformations More than just an updated compilation of progress in the applied science of boron, this book is a tribute to the legions of workers who have spent years conducting groundbreaking studies. The book celebrates these scientists and their protégés, who together transformed boron science into the exciting and growing area it is today.

Polymer Synthesis

Polymer Synthesis
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2004-10-08
  • Total pages :214
  • ISBN : 3540217118
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Summary :

The Mizoroki-Heck Reaction

The Mizoroki-Heck Reaction
  • Author : Martin Oestreich
  • Publisher :Unknown
  • Release Date :2009-02-11
  • Total pages :608
  • ISBN : 0470716061
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Summary : Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)

Cross-coupling Reactions

Cross-coupling Reactions
  • Author : Joffrey Vrijdag
  • Publisher :Unknown
  • Release Date :2020
  • Total pages :268
  • ISBN : 1536176788
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Summary : "Cross-Coupling Reactions: An Overview opens with an overview of the fundamentals and applications of the young and fast developing area of transition metal catalyzed/mediated oxidative (dehydrogenative) C-H/C-H coupling reactions between two (hetero)arenes. Continuing, the authors highlight the recent advances regarding the ligand supported transition metal-catalyzed domino (cascade) or one-pot syntheses of various heterocycles involving cross-coupling reactions. The recent advances in Cu catalyzed tandem reactions for heterocycle synthesis are also addressed. Cu metal chemistry has garnered attention as a potential alternative to precious transition metals, being cheaper, more sustainable and more easily available. A comprehensive account of research on green chemical routes is provided, involving various palladium metal-based catalysts utilized in facilitating cross-coupling reaction in aqueous media. Reported decarboxylative cross-coupling reactions are discussed along with suitable examples, focusing on their mechanism of action"--

The Development of Free Radical-mediated Aryl Amination and Its Application Toward the Total Synthesis of Ambiguine G Nitrile

The Development of Free Radical-mediated Aryl Amination and Its Application Toward the Total Synthesis of Ambiguine G Nitrile
  • Author : Rajesh Viswanathan
  • Publisher :Unknown
  • Release Date :2005
  • Total pages :382
  • ISBN : IND:30000094866609
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Summary :

Organosilicon Chemistry

Organosilicon Chemistry
  • Author : Tamejiro Hiyama,Martin Oestreich
  • Publisher :Unknown
  • Release Date :2020-01-07
  • Total pages :568
  • ISBN : 9783527344536
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Summary : Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides
  • Author : Anant R. Kapdi,Debabrata Maiti,Yogesh S. Sanghvi
  • Publisher :Unknown
  • Release Date :2018-06-04
  • Total pages :358
  • ISBN : 9780128112939
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Summary : Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides describes the procedures and protocols related to the modification of nucleosides, nucleotides and oligonucleotides via Pd-mediated cross-coupling processes. The book highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist this development. Users will find key synthetic protocols for these reactions in this latest volume in the Latest Trends in Palladium Chemistry series. As most of the research in the field of antiviral agents has centered on the use of modified nucleosides that have exhibited promising activity, this book provides an up-to-date reference for both professionals in industry and other interested parties. Provides synthetic routes for useful nucleoside molecules, information otherwise found only through time-consuming literature searches Covers metal-mediated and metal-catalyzed cross coupling processes of nucleosides and related compounds Includes Suzuki-Miyaura, Stille and Sonogashira reactions, as well as C-H bond functionalization Highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist

Amino Group Chemistry

Amino Group Chemistry
  • Author : Alfredo Ricci
  • Publisher :Unknown
  • Release Date :2008-06-25
  • Total pages :408
  • ISBN : 9783527621279
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Summary : Here, probably the most important functional group in organic chemistry is discussed in one handy volume. The monograph covers its application -- from natural products to synthetic pharmaceuticals -- detailing complex syntheses using the amino group as templates and modern techniques focussing on the introduction of the amino group. A definitive must-have for every chemist.

Heterocyclic N-Oxides

Heterocyclic N-Oxides
  • Author : Oleg V. Larionov
  • Publisher :Unknown
  • Release Date :2017-07-12
  • Total pages :157
  • ISBN : 9783319606873
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Summary : The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal.

Organometallic Reagents in Organic Synthesis

Organometallic Reagents in Organic Synthesis
  • Author : John H. Bateson,John E. Bateson,Mike B. Mitchell
  • Publisher :Unknown
  • Release Date :1994
  • Total pages :284
  • ISBN : UOM:39015009124556
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Summary : Organometallic chemistry has always been an important part of organic chemistry, but never more so than today. The expansion of synthetic methodology employing organometallic reagents and metallo-species in the lasttwenty years has been phenomenal.Two major important roles which organometallic reagents play are:Providing a means of activating small molecules like O2, CO, HCN and H2 into larger structuresConferring diastereo-and enantioselectivity.The applications of these reagents in synthesis ranges from the synthesis of drug candidates to the design of efficient large-scale chemical processes.This book brings together experts across the whole range of fields associated with organometallic chemistry to provide a spectrum of up-to-date information.It will be of interest to organic chemists and medicinal chemists in academia and the pharmaceutical industry.

Comprehensive Organic Synthesis

Comprehensive Organic Synthesis
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2014-02-14
  • Total pages :9806
  • ISBN : 9780080977430
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Summary : The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Palladium in Organic Synthesis

Palladium in Organic Synthesis
  • Author : Jiro Tsuji
  • Publisher :Unknown
  • Release Date :2005-07-06
  • Total pages :332
  • ISBN : 3540239820
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Summary : with contributions by numerous experts

Book of Abstracts

Book of Abstracts
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2000
  • Total pages :229
  • ISBN : PSU:000043534425
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Summary :

Modern Catalytic Methods for Organic Synthesis with Diazo Compounds

Modern Catalytic Methods for Organic Synthesis with Diazo Compounds
  • Author : Michael P Doyle,Michael P. Doyle,M. Anthony McKervey,Tao Ye
  • Publisher :Unknown
  • Release Date :1998-01-19
  • Total pages :652
  • ISBN : UOM:39015040598354
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Summary : This much-needed resource brings together a wealth of procedures for the synthesis and practical use of diazocarbonyl compounds. It features methods for the preparation of important catalysts and for applications of diazocarbonyl compounds within each of the main transformation categories-including in-depth coverage of cyclopropanation, C-H and X-H insertion, Wolff rearrangement, ylide formation, aromatic cycloaddition and substitution, and many other useful reactions. Written by leading experts in the field, this book contains cutting-edge material on highly enantioselective transformations, and presents new ways of thinking about diazocarbonyl compounds and their applications, from donor-acceptor cyclopropanes in organic synthesis to macrocyclic cyclopropanation. Complete with illustrative examples of procedures in each chapter, clear diagrams, and a detailed bibliography, this practical reference gives readers the tools they need to put diazocarbonyl compounds to work for their own projects-an invaluable source of guidance for synthetic organic chemists, chemical scientists, and advanced students.