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Metal-Organic Frameworks (MOFs) for Environmental Applications

Metal-Organic Frameworks (MOFs) for Environmental Applications
  • Author : Sujit K. Ghosh
  • Publisher :Unknown
  • Release Date :2019-06-07
  • Total pages :464
  • ISBN : 9780128146347
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Summary : Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. Examines the applications of metal-organic frameworks for the remediation of environmental pollutants Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China Explores possible solutions to some of today’s most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science

Applications of Metal-Organic Frameworks and Their Derived Materials

Applications of Metal-Organic Frameworks and Their Derived Materials
  • Author : Inamuddin,Rajender Boddula,Mohd Imran Ahamed,Abdullah M. Asiri
  • Publisher :Unknown
  • Release Date :2020-06-10
  • Total pages :496
  • ISBN : 9781119650980
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Summary : Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.

Metal-Organic Frameworks

Metal-Organic Frameworks
  • Author : Jianwen Jiang
  • Publisher :Unknown
  • Release Date :2015-01-28
  • Total pages :578
  • ISBN : 9789814613460
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Summary : Metal-organic frameworks (MOFs) have emerged as a new family of nanoporous materials. With an enormous choice of inorganic/organic building blocks, MOFs possess a wide range of surface area, pore size, and functionality and, thus, have been considered versatile materials for many potential applications. This book presents a broad collection of recent modeling studies in the field of MOFs toward potential engineering applications, such as gas storage/separation, carbon capture, catalysis, water purification, and drug delivery. The subject of this book renders it unique, for while the various topics on MOFs boast vast literature, there is not yet a single coherent collection for modeling endeavors. The book will appeal to scientists, engineers, and students in the multidisciplinary intersections of materials science, chemistry, and engineering.

Elaboration And Applications Of Metal-organic Frameworks

Elaboration And Applications Of Metal-organic Frameworks
  • Author : Ma Shengqian,Perman Jason A
  • Publisher :Unknown
  • Release Date :2018-01-29
  • Total pages :732
  • ISBN : 9789813226746
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Summary :

Photocatalytic Functional Materials for Environmental Remediation

Photocatalytic Functional Materials for Environmental Remediation
  • Author : Alagarsamy Pandikumar,Kandasamy Jothivenkatachalam
  • Publisher :Unknown
  • Release Date :2019-07-11
  • Total pages :380
  • ISBN : 9781119529842
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Summary : A comprehensive volume on photocatalytic functional materials for environmental remediation As the need for removing large amounts of pollution and contamination in air, soil, and water grows, emerging technologies in the field of environmental remediation are of increasing importance. The use of photocatalysis—a green technology with enormous potential to resolve the issues related to environmental pollution—breaks down toxic organic compounds to mineralized products such as carbon dioxide and water. Due to their high performance, ease of fabrication, long-term stability, and low manufacturing costs, photofunctional materials constructed from nanocomposite materials hold great potential for environmental remediation. Photocatalytic Functional Materials for Environmental Remediation examines the development of high performance photofunctional materials for the treatment of environmental pollutants. This timely volume assembles and reviews a broad range of ideas from leading experts in fields of chemistry, physics, nanotechnology, materials science, and engineering. Precise, up-to-date chapters cover both the fundamentals and applications of photocatalytic functional materials. Semiconductor-metal nanocomposites, layered double hydroxides, metal-organic frameworks, polymer nanocomposites, and other photofunctional materials are examined in applications such as carbon dioxide reduction and organic pollutant degradation. Providing interdisciplinary focus to green technology materials for the treatment of environmental pollutants, this important work: Provides comprehensive coverage of various photocatalytic materials for environmental remediation useful for researchers and developers Encompasses both fundamental concepts and applied technology in the field Focuses on novel design and application of photocatalytic materials used for the removal of environmental contaminates and pollution Offers in-depth examination of highly topical green-technology solutions Presents an interdisciplinary approach to environmental remediation Photocatalytic Functional Materials for Environmental Remediation is a vital resource for researchers, engineers, and graduate students in the multi-disciplinary areas of chemistry, physics, nanotechnology, environmental science, materials science, and engineering related to photocatalytic environmental remediation.

Metal-Organic Framework Composites

Metal-Organic Framework Composites
  • Author : Anish Khan
  • Publisher :Unknown
  • Release Date :2019-07-20
  • Total pages :286
  • ISBN : 9781644900284
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Summary : Composites based on Metal-organic frameworks (MOFs) have exceptional physical and chemical properties and offer a great number of advanced applications in such fields as energy storage, energy conversion by catalysis, sensors for environmental applications, environment safety and industrial wastewater treatments. They also have interesting medical applications, such as encapsulation of enzymes. The present book covers design, synthesis and preparation of various MOFs, as well as the resulting product characteristics: homogenous morphology, small size dispersion, high thermal stability and desired surface area.

Metal-Organic Frameworks for Chemical Reactions

Metal-Organic Frameworks for Chemical Reactions
  • Author : Anish Khan,Francis Verpoort,Abdullah M. Asiri,Md Enamul Hoque,Anwar L. Bilgrami,Mohammad Azam,Kadiyala Chandra Babu Naidu
  • Publisher :Unknown
  • Release Date :2021-01-19
  • Total pages :500
  • ISBN : 9780128232620
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Summary : Metal-Organic Frameworks for Chemical Reactions: From Organic Transformations to Energy Applications brings together the latest information on MOFs materials, covering recent technology in the field of manufacturing and design. The book covers different aspects of reactions from energy storage and catalysts, including preparation, design and characterization techniques of MOFs material and applications. This comprehensive resource is ideal for researchers and advanced students studying metal-organic frameworks in academia and industry. Metal-organic frameworks (MOFs) are nanoporous polymers made up of inorganic metal focuses connected by natural ligands. These entities have become a hot area of research because of their exceptional physical and chemical properties that make them useful in different fields, including medicine, energy and the environment. Since combination conditions strongly affect the properties of these compounds, it is especially important to choose an appropriate synthetic technique that produces a product with homogenous morphology, small size dispersion, and high thermal stability. Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structure Includes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitors Features information on using MOFs as a replacement to conventional engineering materials because they are lightweight, less costly, environmentally-friendly and sustainable

Metal-Organic Frameworks

Metal-Organic Frameworks
  • Author : David Farrusseng
  • Publisher :Unknown
  • Release Date :2011-09-19
  • Total pages :414
  • ISBN : 9783527635863
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Summary : An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future - Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification - Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks - Separation and purification of gases by MOFs - Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption - Manufacture of MOF thin films on structured supports for separation and catalysis - Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications - Separation of xylene isomers - Metal-Organic Frameworks as Catalysts for Organic Reactions - Biomedical applications of Metal Organic Frameworks - Metal Organic Frameworks for Biomedical Imaging - Luminescent Metal-Organic Frameworks - Deposition of thin films for sensor applications - Industrial MOF Synthesis - MOF shaping and immobilisation A must-have for every scientist in the field.

Zeolites and Metal-Organic Frameworks

Zeolites and Metal-Organic Frameworks
  • Author : Vincent Blay,Luis Francisco Bobadilla,Alejandro Cabrera
  • Publisher :Unknown
  • Release Date :2018-04-11
  • Total pages :342
  • ISBN : 9462985561
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Summary : Zeolites are natural or synthetic materials with porous chemical structures that are valuable due to their absorptive and catalytic qualities. Metal-Organic Frameworks (MOFs) are manmade organometallic polymers with similar porous structures. This introductory book, with contributions from top-class researchers from all around the world, examines these materials and explains the different synthetic routes available to prepare zeolites and MOFs. The book also highlights how the substances are similar yet different and how they are used by science and industry in situations ranging from fueling cars to producing drugs.

Metal-Organic Frameworks in Biomedical and Environmental Field

Metal-Organic Frameworks in Biomedical and Environmental Field
  • Author : Patricia Horcajada Cortés,Sara Rojas Macías
  • Publisher :Unknown
  • Release Date :2021-04-25
  • Total pages :505
  • ISBN : 3030633799
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Summary : This book joins an international and interdisciplinary group of leading experts on the biomedical, energy and environmental applications of Metal-Organic Frameworks (MOFs). The resulting overview covers everything from the environmentally friendly and scale up synthesis of MOFs, their application in green energy generation and storage, and water purification to their use as drug delivery systems, biosensors, and their association with relevant macromolecules (genes, enzymes). This book is focused on the interest of MOFs in applications such as the leading –edge environmental (energy-related) and biomedical fields. The potential of MOFs in these areas is currently progressing at a fast pace, since the wide possibilities that MOFs offer in terms of composition, topology, incorporation of active species (in their porosity, on their external surface or within the framework), and post-synthetic modifications, among others. The aim here is to provide future research goals that emphasize relevant nuances to this class of materials as a whole.

Metal Organic Frameworks

Metal Organic Frameworks
  • Author : Victoria Samanidou,Eleni Deliyanni
  • Publisher :Unknown
  • Release Date :2020-03-27
  • Total pages :198
  • ISBN : 9783039284863
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Summary : Metal–organic frameworks are among the most promising novel materials. The concept of MOFs was first introduced in 1990. They were actually initially used in catalysis, gas separation, membranes, electrochemical sensors. Later on, they were introduced as SPE sorbents for PAHs (Polycyclic Aromatic Hydrocarbons) in environmental water samples, then the range expanded to the field of analytical chemistry, both in chromatographic separation and sample preparation, with great success in, e.g., SPE and SPME (Solid Phase Mico-extraction). Since then, the number of analytical applications implementing MOFs as sorbents in sorptive sample preparation approaches is increasing. Τhis is reinforced by the fact that, at least theoretically, an infinite number of structures can be designed and synthesized, thus making tuneability one of the most unique characteristics of MOF materials. Moreover, they have been designed in various shapes, such as columns, fibers, and films, so that they can meet more analytical challenges with improved analytical features.Their exceptional properties attracted the interest of analytical chemists who have taken advantage of the unique structures and properties and have already introduced them in several sample pretreatment techniques, such as solid phase extraction, dispersive SPE, magnetic solid phase extraction, solid phase microextraction, stir bar sorptive extraction, etc.

Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare

Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare
  • Author : Alexander Samokhvalov
  • Publisher :Unknown
  • Release Date :2017-04-07
  • Total pages :216
  • ISBN : 9781315350417
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Summary : Adsorption and desorption in solution play significant roles in separations, detoxification of waste streams, in purification, chromatography, heterogeneous catalysis, metabolism of medicinal drugs, and beyond. Metal-Organic Frameworks (MOFs) are well-ordered 3-dimensional hybrid organic-inorganic polymers which contain metal cations and the structure-building organic "linker" units. Mesoporous MOFs with pore sizes 2-50 nm are particularly suitable for adsorption and adsorption-based separations of large molecules of organic and bio-organic compounds. Thousands of organic compounds and, in particular, aromatic and heterocyclic compounds are widely used as feedstock for industrial chemical synthesis, as fine chemicals, major components of liquid fossil fuels, dyestuffs, industrial solvents, agricultural chemicals, medicinal drugs, pharmaceuticals and personal care products (PPCPs), and active pharmaceutical ingredients (APIs). There is a strong interest towards synthesis, characterization and studies of both known and newly synthesized mesoporous MOFs for adsorption in solution to achieve the high adsorption capacity, selectivity, and the possibility of multiple regeneration of "spent" sorbent. This book covers experimental fundamental research on using mesoporous MOFs in emerging applications of major industrial, environmental and academic importance, especially purification of water and liquid fossil fuels and in advanced biomedical technologies.

Metal-Organic Frameworks

Metal-Organic Frameworks
  • Author : Fahmina Zafar,Eram Sharmin
  • Publisher :Unknown
  • Release Date :2016-10-12
  • Total pages :166
  • ISBN : 9789535126621
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Summary : The emerging and interesting field of MOF encouraged us to bring forth the book titled ''Metal Organic Frameworks''. The book is divided into three sections. Section A consists of introduction, Section B comprises the synthesis and characterization techniques, and Section C is dedicated to the applications of MOFs. The book would be useful for scientists and researchers interested in the field of MOFs.

Metal-Organic Frameworks

Metal-Organic Frameworks
  • Author : Hermenegildo García,Sergio Navalón
  • Publisher :Unknown
  • Release Date :2018-02-27
  • Total pages :536
  • ISBN : 9783527809103
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Summary : Focusing on applications in separation, adsorption and catalysis, this handbook underlines the importance of this hot and exciting topic. It provides an excellent insight into the synthesis and modification of MOFs, their synthesis on an industrial scale, their use as CO2 and chemical warfare adsorbers, and the role of defects in catalysis. In addition, the authors treat such new aspects as biocatalysis and applications in photocatalysis and optoelectronic devices.

Metal-Organic Frameworks

Metal-Organic Frameworks
  • Author : Lars Öhrström,Francoise M. Amombo Noa
  • Publisher :Unknown
  • Release Date :2021-03-25
  • Total pages :229
  • ISBN : 9780841299047
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Summary : Some 80,000 metal-organic frameworks (MOFs) have been reported as of 2020. With intriguing structures and fascinating properties, MOFs are poised to be a defining material of the 21st century with a great deal of commercial potential from methane fuel automobile tanks to carbon capturing. Metal-Organic Frameworks provides an introduction to the complex world of MOFs. Researchers new to MOFs can use this work as a jumping-off point for theoretical study or applied research. The work is broad and expansive in scope, but inclusive and comprehensive in detail. The authors provide a personal perspective of MOF research that provides a strong foundation in the basic methods and themes as well as directs the reader in how to think about MOFs. Sixteen MOF structures are animated, providing more clarity into the dimensionality of MOFs. Accompanying links take the reader to additional 3-D structures provided by The Cambridge Crystallographic Data Centre (CCDC).

Introduction to Reticular Chemistry

Introduction to Reticular Chemistry
  • Author : Omar M. Yaghi,Markus J. Kalmutzki,Christian S. Diercks
  • Publisher :Unknown
  • Release Date :2019-03-22
  • Total pages :552
  • ISBN : 9783527821105
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Summary : A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.

Advanced Catalytic Materials

Advanced Catalytic Materials
  • Author : Noreña Luis,Jin-An Wang
  • Publisher :Unknown
  • Release Date :2016-02-03
  • Total pages :498
  • ISBN : 9789535122449
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Summary : Todays chemical industry processes worldwide largely depend on catalytic reactions and the desirable future evolution of this industry toward more selective products, more environmentally friendly products, more energy-efficient processes, a smaller use of hazardous reagents, and a better use of raw materials also largely involves the development of better catalysts and, specifically, purposely designed catalytic materials. The careful study and development of the new-generation catalysts involve relatively large groups of specialists in universities, research centers, and industries, joining forces from different scientific and technical disciplines. This book has put together recent, state-of-the-art topics on current trends in catalytic materials and consists of 16 chapters.

Pillared Metal-Organic Frameworks

Pillared Metal-Organic Frameworks
  • Author : Lida Hashemi,Ali Morsali
  • Publisher :Unknown
  • Release Date :2019-04-30
  • Total pages :378
  • ISBN : 9781119460244
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Summary : In the last two decades, metal-organic frameworks (MOFs) have provoked considerable interest due to their potential applications in different fields such as catalysis, gas storage and sensing. The most important advantages of MOFs over other porous materials is the ability of tailoring their pore size, functionality and even the topology of the framework by rational selection of the molecular building blocks. Therefore, many chemists have tried to engineer the structure of MOFs to achieve specific functions. Pillared metal organic frameworks are a class of MOFs composed of inorganic secondary building units (SBUs) and two sets of organic linkers, generally oxygen- and nitrogen-donor ligands. Typically, in the structure of pillared MOFs, the oxygen-donor struts link the metal clusters into a two-dimensional (2D) sheet and the N-donor struts pillar the sheets to generate a three-dimensional (3D) framework. Thus, the construction of MOFs by utilizing two sets of organic linkers could provide an extra possibility for further tuning of MOF’s pore walls. A variety of functional groups including imine, amide and heterocycles were successfully incorporated into bidentate pillar ligand skeleton. Interestingly, by using pillaring linkers with different length, a wide diversity of metal-organic frameworks with tunable pore dimensions and topologies can be obtained. In this book, we introduce pillared metal organic frameworks with their properties and applications.

Metal-Organic Frameworks

Metal-Organic Frameworks
  • Author : Leonard R. MacGillivray
  • Publisher :Unknown
  • Release Date :2010-12-17
  • Total pages :349
  • ISBN : 111803516X
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Summary : Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.

The Chemistry of Metal-Organic Frameworks

The Chemistry of Metal-Organic Frameworks
  • Author : Stefan Kaskel
  • Publisher :Unknown
  • Release Date :2016-06-14
  • Total pages :904
  • ISBN : 9783527693085
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Summary : Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.

Metal-Organic Framework Materials

Metal-Organic Framework Materials
  • Author : Leonard R. MacGillivray,Charles M. Lukehart
  • Publisher :Unknown
  • Release Date :2014-09-19
  • Total pages :592
  • ISBN : 9781118931585
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Summary : Metal-Organic Frameworks (MOFs) are crystalline compoundsconsisting of rigid organic molecules held together and organizedby metal ions or clusters. Special interests in these materialsarise from the fact that many are highly porous and can be used forstorage of small molecules, for example H2 orCO2. Consequently, the materials are ideal candidatesfor a wide range of applications including gas storage, separationtechnologies and catalysis. Potential applications includethe storage of hydrogen for fuel-cell cars, and the removal andstorage of carbon dioxide in sustainable technical processes. MOFsoffer the inorganic chemist and materials scientist a wide range ofnew synthetic possibilities and open the doors to new and excitingbasic research. Metal-Organic Frameworks Materials provides a solid basisfor the understanding of MOFs and insights into new inorganicmaterials structures and properties. The volume also reflectsprogress that has been made in recent years, presenting a widerange of new applications including state-of-the art developmentsin the promising technology for alternative fuels. Thecomprehensive volume investigates structures, symmetry,supramolecular chemistry, surface engineering, recognition,properties, and reactions. The content from this book will be added online to theEncyclopedia of Inorganic and Bioinorganic Chemistry: ahref="http://www.wileyonlinelibrary.com/ref/eibc"http://www.wileyonlinelibrary.com/ref/eibc/a