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Organotransition Metal Chemistry: Applications to Organic Synthesis

Organotransition Metal Chemistry: Applications to Organic Synthesis
  • Author : S. G. Davies
  • Publisher :Unknown
  • Release Date :2013-10-22
  • Total pages :430
  • ISBN : 9781483285849
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Summary : Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Organotransition Metal Chemistry: From Bonding to Catalysis

Organotransition Metal Chemistry: From Bonding to Catalysis
  • Author : John F. Hartwig
  • Publisher :Unknown
  • Release Date :2010-02-10
  • Total pages :1127
  • ISBN : UCSD:31822037482676
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Summary : Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.

Organotransition Metals in Organic Synthesis

Organotransition Metals in Organic Synthesis
  • Author : Sugata Chatterjee
  • Publisher :Unknown
  • Release Date :2020-12-15
  • Total pages :315
  • ISBN : 0128184779
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Summary : Organotransition Metals in Organic Synthesis: Fundamentals and Applications provides a fundamental understanding on how to use transition and main group metals to synthesize simple and complex molecules with a high degree of selectivity. This book details the basic concepts, elementary reactions, and latest developments of organometallic chemistry surrounding the transition metals. Topics covered include electronic configuration and structural, methods for carbon-transition metal bond creation, cleavage of metal-carbon bonds to form new carbon-carbon bonds, chemo-, region-, stereo- and enantio- control, and heterogeneous organometallic reactions. This book is an ideal resource for researchers and students working with metals in organic synthesis and organometallic chemistry, including those having no prior exposure to organometallic chemistry in synthesis. Includes extensive coverage of methods for creating carbon-transition metal bonds, such as oxidative addition, oxidative coupling, hydro and carbometallation, carbonyl insertion, transmetallation and metal carbenes and metathesis Ideal for students and researchers new to the pharmaceutical industry or organometallic chemistry in general, covering foundational information as well as select advanced applications Covers metals in organic synthesis, unprecedented selectivity, clean reactions, mild conditions, high yields, along with improvisation methods for existing synthesis methods

Organotransition Metal Chemistry

Organotransition Metal Chemistry
  • Author : Akio Yamamoto
  • Publisher :Unknown
  • Release Date :1986
  • Total pages :455
  • ISBN : UOM:39015055710563
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Summary : A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics. Well illustrated with figures and formulae.

Organotransition Metal Chemistry A Mechanistic Approach

Organotransition Metal Chemistry A Mechanistic Approach
  • Author : Richard Heck
  • Publisher :Unknown
  • Release Date :2012-12-02
  • Total pages :350
  • ISBN : 9780323154703
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Summary : Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal δ- and π-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.

New Pathways for Organic Synthesis

New Pathways for Organic Synthesis
  • Author : H.M. Colquhoun,J. Holton,D.J. Thompson,M.V. Twigg
  • Publisher :Unknown
  • Release Date :2012-12-06
  • Total pages :468
  • ISBN : 9781461326519
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Summary : The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.

Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules
  • Author : Louis S. Hegedus
  • Publisher :Unknown
  • Release Date :1999
  • Total pages :337
  • ISBN : 1891389041
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Summary : This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Transition Metal Reagents and Catalysts

Transition Metal Reagents and Catalysts
  • Author : Jiro Tsuji
  • Publisher :Unknown
  • Release Date :2002-08-16
  • Total pages :496
  • ISBN : 0471560278
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Summary : Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complex chemistry * An in-depth treatment of many innovative synthetic methodologies * A rational classification of all reactions according to substrates and reaction mechanisms * Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists. Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.

Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis

Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis
  • Author : B. L. Shaw,N. I. Tucker
  • Publisher :Unknown
  • Release Date :2016-06-06
  • Total pages :229
  • ISBN : 9781483181714
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Summary : Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis covers compounds that possess carbon atoms bonded to metal and to other carbon atoms. The order in which the substances appear in the book is based on the number of carbon atoms it have. The first section is about the alkyl, aryl, ethynyl, acyl, and carbene complexes. The second section deals with olefin and chelating diolefin complexes and complexes formed from acetylene. The following section covers the π-allylic complexes. The structures, stability, and bonding of alkyl and aryl complexes are fully covered. The magnetic moments and electronic spectra are discussed in detail.The fourth section discusses the conjugated diolefinic complexes that contain butadiene or cyclobutadiene. The rest of the book focuses on cyclopentadienyls, arene complexes, tropylium complexes, and complexes formed from cyclo-octatetraene or azulene. The book will be a useful tool for chemists, chemical engineers, and students and researchers in the field of chemistry.

Organotransition-Metal Chemistry

Organotransition-Metal Chemistry
  • Author : Yoshio Ishii
  • Publisher :Unknown
  • Release Date :2012-03-19
  • Total pages :398
  • ISBN : 1468421441
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Summary : In every generation the achievements in science have served mankind. The progress accomplished by one generation stimulates the next generation to even greater achievements, which may take the form of increasing, crystallizing, or detailing existing theo ries. Other forms, generally resulting from persistence and enlight ened fortune, open new areas of investigation previously unimagined and have an impact that may be felt for many years. An example of this latter form of achievement was the prepara tion and elucidation of the structures of dicyclopentadienyliron (ferrocene, reported in 1951) dibenzenechromium iodide, triphenyl chromium tristetrahydrofuranate, and numerous olefin-metal ~-com plexes which provided an introduction to new types of chemical bonds the sigma carbon-transition metal bond and the metal ~-complex bond. Initial progress in the field of organotransition-metal chemis try followed the lines of interest generated separately by organic and inorganic chemistry. However, it is becoming increasingly clear that organotransit10n-metal chemistry is not only bridging these two fields, but also crosslinking many other fields of science.

The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals
  • Author : Robert H. Crabtree
  • Publisher :Unknown
  • Release Date :2005-06-14
  • Total pages :600
  • ISBN : 9780471718758
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Summary : Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.

Organotransition Metal Chemistry

Organotransition Metal Chemistry
  • Author : Anthony F. Hill,A. Hill
  • Publisher :Unknown
  • Release Date :2002
  • Total pages :185
  • ISBN : 0854046224
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Summary : This book aims to introduce undergraduates to the utility of organotransition metal chemistry, a discipline of importance to scientists in a variety of industry sectors.

Principles and Applications of Organotransition Metal Chemistry

Principles and Applications of Organotransition Metal Chemistry
  • Author : James Paddock Collman,Louis S. Hegedus,Jack R. Norton,Richard G. Finke
  • Publisher :Unknown
  • Release Date :1987
  • Total pages :989
  • ISBN : UOM:49015000654302
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Summary : This textbook introduces students and experienced chemists to a rapidly growing interdisciplinary subject. It incorporates a thorough revision of the earlier edition, and includes all new developments.

Principles of Organometallic Chemistry

Principles of Organometallic Chemistry
  • Author : G. E. Coates
  • Publisher :Unknown
  • Release Date :2012-12-06
  • Total pages :258
  • ISBN : 9789401096812
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Summary : The second edition of Organometallic Compounds (1960) was used not only by specialists but also as an undergraduate textbook. The third edition, recently published in two volumes, is about three times the length of the second and contains considerably more factual material than is appropriate for a student textbook. Therefore we believe that a shorter treatment would be welcome. In planning this book the authors have emphasized matters more of prin ciple than of detail, and have included in the first two chapters some general discussion of the properties and syntheses of organometallic compounds that is not to be found in the larger work. Some aspects of the organic chemistry of arsenic, and of silicon with particular reference to silicone polymers, are also included. Most university teachers of chemistry are becoming seriously concerned about the relentless increase in the amount and complexity of the material that is squeezed into undergraduate chemistry courses. With this in mind the authors have tried to cut detail to a minimum, but readers will find that the relative amount presented varies considerably between the various topics discussed. In general the treatment is more extensive than usual only if either or both of these conditions are met: (1), the subject has significant bearing on other major branches of chemistry including im portant industrial processes; (2), the topic is commonly misunderstood or found to be confusing.

Applications of Organo-transition Metal Complexes in Organic Synthesis

Applications of Organo-transition Metal Complexes in Organic Synthesis
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :1986*
  • Total pages :83
  • ISBN : OCLC:70387649
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Summary :

Asymmetric Induction in Organo-transition Metal Complexes

Asymmetric Induction in Organo-transition Metal Complexes
  • Author : Brian Arthur Roden
  • Publisher :Unknown
  • Release Date :1989
  • Total pages :508
  • ISBN : OCLC:20785939
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Summary :

Transition Metals in Organic Synthesis

Transition Metals in Organic Synthesis
  • Author : Rolf Scheffold
  • Publisher :Unknown
  • Release Date :1983
  • Total pages :440
  • ISBN : UOM:39015016094180
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Summary :

The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals
  • Author : Robert H. Crabtree
  • Publisher :Unknown
  • Release Date :2011-09-20
  • Total pages :520
  • ISBN : 9781118210857
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Summary :

Landmarks in Organo-Transition Metal Chemistry

Landmarks in Organo-Transition Metal Chemistry
  • Author : Helmut Werner
  • Publisher :Unknown
  • Release Date :2008-12-16
  • Total pages :348
  • ISBN : 9780387098487
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Summary : Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.

Pincer and Pincer-Type Complexes

Pincer and Pincer-Type Complexes
  • Author : Kálmán J. Szabó,Ola F. Wendt
  • Publisher :Unknown
  • Release Date :2014-06-10
  • Total pages :320
  • ISBN : 9783527681334
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Summary : This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.

Organometallic Mechanisms and Catalysis

Organometallic Mechanisms and Catalysis
  • Author : Jay Kochi
  • Publisher :Unknown
  • Release Date :2012-12-02
  • Total pages :642
  • ISBN : 9780323144100
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Summary : Organometallic Mechanisms and Catalysis: The Role of Reactive Intermediates in Organic Processes covers the mechanistic delineation of organometallic chemistry and catalysis. This book is organized into three parts encompassing 18 chapters. The first part describes first the oxidation-reduction process of organometals, followed by discussions on the catalytic reactions of peroxides, metal-catalyzed addition to olefins, and reduction of organic halides. This part also explores other reactions involving transition metal carbonyls and metal-catalyzed reactions of aromatic diazonium salts. The second part deals with some chemical aspects of organometals, such as their stability, thermochemistry, decomposition, hemolytic pathways, and the formation of carbon-carbon bonds. The third part examines the charge transfer processes and interactions of organometals with electron acceptors. This part further looks into the cleavage and insertion reactions of organometals with electrophiles, as well as the electrophilic and electron transfer mechanisms of organometals. Organic and inorganic chemists, teachers, and students will greatly benefit from this book.