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Rotational Structure in Molecular Infrared Spectra

Rotational Structure in Molecular Infrared Spectra
  • Author : Carlo di Lauro
  • Publisher :Unknown
  • Release Date :2020-05-17
  • Total pages :356
  • ISBN : 0128223944
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Summary : Rotational Structure in Molecular Infrared Spectra, Second Edition, fills the gap between these complex topics and the most elementary methods in the field of rotational structure in the infrared spectra of gaseous molecules. Combining foundational theoretical information with advanced applications, this book is a useful guide for all those involved in the application of molecular spectroscopic techniques and the interpretation of vibration-rotation spectra. Interpreting vibration-rotation spectra is an important skill in many scientific disciplines, ranging from nanochemistry to planetary research, hence this book is an ideal resource. Includes new content on the interaction of rotation and nuclear electric quadrupoles, coupled and uncoupled nuclei, and internal rotation from the high-barrier basis limit Provides updated tables and figures throughout to support the knowledge outlined in the text Outlines different paths through the text to help readers from different backgrounds explore the most appropriate content for their needs

Rotational Structure in Molecular Infrared Spectra

Rotational Structure in Molecular Infrared Spectra
  • Author : Carlo di Lauro
  • Publisher :Unknown
  • Release Date :2013-04-27
  • Total pages :344
  • ISBN : 0124078931
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Summary : Recent advances in infrared molecular spectroscopy have resulted in sophisticated theoretical and laboratory methods that are difficult to grasp without a solid understanding of the basic principles and underlying theory of vibration-rotation absorption spectroscopy. Rotational Structure in Molecular Infrared Spectra fills the gap between these recent, complex topics and the most elementary methods in the field of rotational structure in the infrared spectra of gaseous molecules. There is an increasing need for people with the skills and knowledge to interpret vibration-rotation spectra in many scientific disciplines, including applications in atmospheric and planetary research. Consequently, the basic principles of vibration-rotation absorption spectroscopy are addressed for contemporary applications. In addition to covering operational quantum mechanical methods, spherical tensor algebra, and group theoretical methods applied to molecular symmetry, attention is also given to phase conventions and their effects on the values of matrix elements. Designed for researchers and PhD students involved in the interpretation of vibration-rotation spectra, the book intentionally separates basic theoretical arguments (in the appendices), allowing readers who are mainly concerned with applications to skip the principles while at the same time providing a sound theoretical basis for readers who are looking for more foundational information. Reviews basic theory and contemporary methods of vibration rotation absorption spectroscopy, including operational quantum mechanical methods, spherical tensor algebra, and group theoretical methods applied to molecular symmetry Covers sophisticated mathematical topics in simple, easy-to-read language Discusses methods and applications separately from basic theoretical arguments for quick reference

Rotational Spectra and Molecular Structure

Rotational Spectra and Molecular Structure
  • Author : James E. Wollrab
  • Publisher :Unknown
  • Release Date :2016-10-27
  • Total pages :484
  • ISBN : 148319485X
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Summary : Physical Chemistry, A Series of Monographs: Rotational Spectra and Molecular Structure covers the energy levels and rotational transitions. This book is divided into nine chapters that evaluate the rigid asymmetric top molecules and the nuclear spin statistics for asymmetric tops. Some of the topics covered in the book are the asymmetric rotor functions; rotational transition intensities; classes of molecules; nuclear spin statistics for linear molecules and symmetric tops; and classical appearance of centrifugal and coriolis forces. Other chapters deal with the energy levels and effects of centrifugal distortion, as well as the internuclear distance and moments of inertia. The discussion then shifts to the coriolis coupling effects on rotational constants and the perturbation treatment of vibration-rotational Hamiltonian. The last chapter is devoted to the examination of origin of the quadrupole interaction. The book can provide useful information to chemists, physicists, electrical engineers, students, and researchers.

Vibrational Spectroscopy

Vibrational Spectroscopy
  • Author : D. N. Sathyanarayana
  • Publisher :Unknown
  • Release Date :2015-07
  • Total pages :692
  • ISBN : 9788122415179
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Summary : Vibrational Spectroscopy Provides In A Very Readable Fashion A Comprehensive Account Of The Fundamental Principles Of Infrared And Raman Spectroscopy For Structural Applications To Inorganic, Organic And Coordination Compounds. Theoretical Analyses Of The Spectra By Normal Coordinate Treatment, Factor Group Analysis And Molecular Mechanics Are Delineated.The Book Features: * Coverage From First Principles To Recent Advances * Relatively Self-Contained Chapters * Experimental Aspects * Step By Step Treatment Of Molecular Symmetry And Group Theory * Recent Developments Such As Non-Linear Raman Effects * Comprehensive Treatment Of Rotation Spectroscopy * Band Intensities * Spectra Of Crystals * End-Of-Chapter Exercises.Suitable For Students And Researchers Interested In The Field Of Vibrational Spectroscopy. No Prior Knowledge Of Concepts Specific To Vibrational Spectroscopy Is Necessary. Mathematical Background Such As Matrices And Vectors Are Provided.

THE FAR INFRARED ABSORPTION SPECTRUM AND THE ROTATIONAL STRUCTURE OF THE HEAVY WATER VAPOR MOLECULE.

THE FAR INFRARED ABSORPTION SPECTRUM AND THE ROTATIONAL STRUCTURE OF THE HEAVY WATER VAPOR MOLECULE.
  • Author : Nelson Fuson
  • Publisher :Unknown
  • Release Date :1939
  • Total pages :229
  • ISBN : 09876543XX
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Summary :

Basic Atomic and Molecular Spectroscopy

Basic Atomic and Molecular Spectroscopy
  • Author : John Michael Hollas
  • Publisher :Unknown
  • Release Date :2002
  • Total pages :184
  • ISBN : 9780854046676
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Summary : The latest in the 'Tutorial Chemistry Texts' series, 'Basic Atomic and Molecular Spectroscopy' contains chapters on quantization in polyelectronic atoms, molecular vibrations and electronic spectroscopy.

NBS Special Publication

NBS Special Publication
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :1968
  • Total pages :229
  • ISBN : 09876543XX
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Summary :

Publications

Publications
  • Author : United States. National Bureau of Standards
  • Publisher :Unknown
  • Release Date :1978
  • Total pages :229
  • ISBN : 09876543XX
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Summary :

Catalog of National Bureau of Standards Publications, 1966-1976

Catalog of National Bureau of Standards Publications, 1966-1976
  • Author : United States. National Bureau of Standards
  • Publisher :Unknown
  • Release Date :1978
  • Total pages :229
  • ISBN : 09876543XX
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Summary :

Frontiers of Molecular Spectroscopy

Frontiers of Molecular Spectroscopy
  • Author : Jaan Laane
  • Publisher :Unknown
  • Release Date :2011-08-11
  • Total pages :740
  • ISBN : 9780080932378
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Summary : Much of what we know about atoms, molecules, and the nature of matter has been obtained using spectroscopy over the last one hundred years or so. In this book we have collected together twenty chapters by eminent scientists from around the world to describe their work at the cutting edge of molecular spectroscopy. These chapters describe new methodology and applications, instrumental developments, and theory which is taking spectroscopy into new frontiers. The range of topics is broad. Lasers are utilized in much of the research, but their applications range from sub-femtosecond spectroscopy to the study of viruses and also to the investigation of art and archeological artifacts. Three chapters discuss work on biological systems and three others represent laser physics. The recent advances in cavity ringdown spectroscopy (CRDS), surface enhanced Raman spectroscopy (SERS), two-dimensional correlation spectroscopy (2D-COS), and microwave techniques are all covered. Chapters on electronic excited states, molecular dynamics, symmetry applications, and neutron scattering are also included and demonstrate the wide utility of spectroscopic techniques. * provides comprehensive coverage of present spectroscopic investigations * features 20 chapters written by leading researchers in the field * covers the important role of molecular spectroscopy in research concerned with chemistry, physics, and biology

Molecular Spectroscopy: Modern Research

Molecular Spectroscopy: Modern Research
  • Author : K.N. Rao
  • Publisher :Unknown
  • Release Date :2012-12-02
  • Total pages :466
  • ISBN : 0323149324
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Summary : Molecular Spectroscopy: Modern Research, Volume III is a collection of papers presented at the 40th Annual Molecular Spectroscopy Symposium, held at the Ohio State University. The contributors of this seven-chapter text cover the significant advances in molecular spectroscopic research and their application in chemistry. Chapters 1 and 2 discuss first the higher-order vibration-rotation interactions in molecules and then present formulas and an insight into the direction being taken in theoretical pursuits. Chapter 3 provides an extensive compilation of published intensity and collision broadening parameters derived from infrared spectra. This chapter also contains a detailed discussion using consistent notation of some of the methods commonly applied to extract such information from laboratory spectra. Chapter 4 examines a variety of laser systems and their application in investigations involving triatomic free radicals and ions, while chapter 5 considers the developments in the microwave spectroscopic studies on nonpolar molecules when their symmetry is reduced by isotopic substitution. Chapter 6 emphasizes the quasi-linear molecular problem to develop an appreciation of the symptoms of quasi-linearity and theoretical treatments thereof. This chapter also examines the increasing role of highly resolved spectra in the interpretation of various large-amplitude motions in molecules. Lastly, Chapter 7 describes the electric multipolar moments of hydrogen and its isotopes. Spectroscopists, chemists, and researchers will find this work invaluable.

Structure of Molecules and Internal Rotation

Structure of Molecules and Internal Rotation
  • Author : San-Ichiro Mizushima
  • Publisher :Unknown
  • Release Date :2013-09-03
  • Total pages :256
  • ISBN : 1483261646
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Summary : Structure of Molecules and Internal Rotation focuses on the processes, methodologies, and reactions involved in internal rotation. The manuscript first offers information on studies on dihalogenoethanes, as well as the spectroscopic and thermal measurements of ethane and its derivatives. Discussions focus on the dielectric constant of halogenoethanes, electron diffraction, Raman effect in ethane derivatives, and entropy difference between rotational isomers. The text also ponders on internal rotation in simple molecules and paraffinic hydrocarbons. The publication examines polypeptides and related compounds and the principles and experimental methods of structure determination. Topics include Raman effect, infrared absorption, molecules with two peptide bonds, and the configuration of a polypeptide chain. The manuscript is a valuable source of data for chemists and readers interested in the structure of molecules and internal rotation.

Molecular Spectra and Molecular Structure: Infrared and Raman spectra of polyatomic molecules

Molecular Spectra and Molecular Structure: Infrared and Raman spectra of polyatomic molecules
  • Author : Gerhard Herzberg
  • Publisher :Unknown
  • Release Date :1939
  • Total pages :229
  • ISBN : 09876543XX
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Summary :

Biophotonics

Biophotonics
  • Author : Matthew Baker,Katherine A. Hollywood,Caryn Hughes
  • Publisher :Unknown
  • Release Date :2016-02-01
  • Total pages :93
  • ISBN : 1681741350
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Summary : Biophotonic diagnostics/biomedical spectroscopy can revolutionise the medical environment by providing a responsive and objective diagnostic environment. This book aims to explain the fundamentals of the physical techniques used combined with the particular requirements of analysing medical/clinical samples as a resource for any interested party. In addition, it will show the potential of this field for the future of medical science and act as a driver for translation across many different biological problems/questions.

Introduction to Infrared and Raman Spectroscopy

Introduction to Infrared and Raman Spectroscopy
  • Author : Norman Colthup
  • Publisher :Unknown
  • Release Date :2012-12-02
  • Total pages :536
  • ISBN : 032316160X
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Summary : Introduction to Infrared and Raman Spectroscopy focuses on the theoretical and experimental aspects of infrared and Raman spectroscopy, with emphasis on detailed group frequency correlations and their vibrational origin. Topics covered include vibrational and rotational spectra, molecular symmetry, methyl and methylene groups, triple bonds and cumulated double bonds, and olefin groups. Aromatic and heteroaromatic rings are also considered, along with carbonyl compounds and molecular vibrations. This book is comprised of 14 chapters and begins with a discussion on the use of Raman and infrared spectroscopy to study the vibrational and rotational frequencies of molecules, paying particular attention to photon energy and degrees of freedom of molecular motion. The quantum mechanical harmonic oscillator and the anharmonic oscillator are described. The next chapter focuses on the experimental techniques and instrumentation needed to measure infrared absorption spectra and Raman spectra. Symmetry is then discussed from the standpoint of the spectroscopist. The following chapters explore the vibrational origin of group frequencies, with an emphasis on mechanical effects; spectra-structure correlations; and the spectra of compounds such as ethers, alcohols, and phenols. The final chapter demonstrates how the frequencies and forms of a nonlinear molecule's normal modes of vibration may be calculated mathematically. This monograph will be a useful resource for spectroscopists and physical scientists.

Fundamentals of Molecular Spectroscopy.

Fundamentals of Molecular Spectroscopy.
  • Author : P S Sindhu
  • Publisher :Unknown
  • Release Date :2006
  • Total pages :426
  • ISBN : 9788122417968
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Summary : The Book Has 15 Chapters In All. The First Two Chapters Are Related To Atomic Structure And Atomic Spectra. The Next Chapter Is Devoted To Nature Of Chemical Bonds As Looked Upon Through Quantum Mechanics, Followed By All Types Of Spectroscopy. Every Aspect Is Explained With Some Typical Spectra. The Underlying Theory So Developed Will Help Students To Carry Out Spectral Analysis.Only Simple Quantum Mechanics Relevant To Simple Molecular Structure Has Been Given. Attempt Has Been Made To Relate The Characteristic Chemical Behavior Of These Molecules With Its Mo And Thus To Molecular Spectra. One Will Not Find Such Relationship In Any Book, But This Will Make Chemistry, As Such, Still More Interesting.Application Of Infrared And Ultra-Violet Spectroscopy, Nmr And Mass Spectra In Structure Determination Of Organic Molecules Are Very Elegantly Presented. In The Fourteenth Chapter, Lasers And Their Applications To Various Types Of Second, Third, And Fourth Order Scattering Spectroscopy Have Been Developed. The Book Has Minimum But Essential Mathematics With Very Easy Format In Its Text. Such An Approach Will Give A Clear Understanding Of The Subject And Provides Knowledge To Excel At Any Level University Examination, Competitive Examination, And Before Interview Boards.

Rotational Spectroscopy of Diatomic Molecules

Rotational Spectroscopy of Diatomic Molecules
  • Author : John Michael Brown,John M. Brown,Alan Carrington
  • Publisher :Unknown
  • Release Date :2003-04-10
  • Total pages :1013
  • ISBN : 9780521530781
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Summary : Table of contents

Introduction to Infrared and Raman Spectroscopy

Introduction to Infrared and Raman Spectroscopy
  • Author : Norman B. Colthup,Lawrence H. Daly,Stephen E. Wiberley
  • Publisher :Unknown
  • Release Date :1990-10-10
  • Total pages :547
  • ISBN : 0080917402
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Summary : Now in its third edition, this classic text covers many aspects of infrared and Raman spectroscopy that are critical to the chemist doing structural or compositional analysis. This work includes practical and theoretical approaches to spectral interpretation as well as a discussion of experimental techniques. Emphasis is given to group frequencies, which are studied in detailed discussions, extensive tables, and over 600 carefully chosen and interpreted spectral examples. Also featured is a unique treatment of group frequencies that stresses their mechanical origin. This qualitative approach to vibrational analysis helps to simplify spectral interpretation. Additional topics include basic instrumental components and sampling techniques, quantitative analysis, Raman polarization data, infrared gas contours, and polarized IR studies, among others. Focuses on group frequency correlations and how to use them in spectral interpretation Revised and updated by a pioneer in the field, Norman Colthup, who for thirty years has served as an expert lecturer for the Fisk Infrared Institute Explores new group frequency studies in aromatics, alkanes and olefins, among others Includes completely updated section on instrumentation

Infrared Spectroscopy of Triatomics for Space Observation

Infrared Spectroscopy of Triatomics for Space Observation
  • Author : Pierre-Richard Dahoo,Azzedine Lakhlifi
  • Publisher :Unknown
  • Release Date :2019-01-23
  • Total pages :236
  • ISBN : 1786303930
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Summary : This book is dedicated to the application of the different theoretical models described in Volume 1 to identify the near-, mid- and far-infrared spectra of linear and nonlinear triatomic molecules in gaseous phase or subjected to environmental constraints, useful for the study of environmental sciences, planetology and astrophysics. The Van Vleck contact transformation method, described in Volume 1, is applied in the calculation and analysis of IR transitions between vibration–rotation energy levels. The extended Lakhlifi–Dahoo substitution model is used in the framework of Liouville’s formalism and the line profiles of triatomic molecules and their isotopologues subjected to environmental constraints are calculated by applying the cumulant expansion. The applications presented in this book show how interactions at the molecular level modify the infrared spectra of triatomics trapped in a nano-cage (substitution site of a rare gas matrix, clathrate, fullerene, zeolite) or adsorbed on a surface, and how these interactions may be used to identify the characteristics of the perturbing environment.

Molecular Spectroscopy: Modern Research

Molecular Spectroscopy: Modern Research
  • Author : K. Narahari Rao,C. Weldon Mathews
  • Publisher :Unknown
  • Release Date :1972
  • Total pages :422
  • ISBN : 09876543XX
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Summary :

Spectrophysics

Spectrophysics
  • Author : Anne Thorne,Ulf Litzén,Sveneric Johansson
  • Publisher :Unknown
  • Release Date :1999-04-01
  • Total pages :434
  • ISBN : 9783540651178
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Summary : Spectrophysics covers those applications of spectroscopy that are directed at investigating the interactions or radiating atoms and molecules with their environment, with particular reference to the fields of astrophysics, plasma physics and atmospheric physics. Much of the material is normally found only in specialized texts.