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Spectral Methods in Transition Metal Complexes

Spectral Methods in Transition Metal Complexes
  • Author : K. Sridharan
  • Publisher :Unknown
  • Release Date :2016-02-13
  • Total pages :202
  • ISBN : 9780128096543
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Summary : Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes. Provides readers with a single reference on metal complexes and coordination compounds Contains more than 100 figures, tables, and illustrations to aid in the retention of key concepts Authored by a scientist with nearly 40 years of experience in research and instruction

Electronic and Vibronic Spectra of Transition Metal Complexes II

Electronic and Vibronic Spectra of Transition Metal Complexes II
  • Author : Hartmut Yersin
  • Publisher :Unknown
  • Release Date :2014-03-12
  • Total pages :262
  • ISBN : 3662147882
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Summary : The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, dÂ*, and ÂÂ* states is given, and a modern ligand field theory based on the Angular Overlap Model is presented. In experimental case studies it is shown how to characterize different types of electronic transitions using modern methods of laser spectroscopy. Consequences of spin-orbit coupling, zero-field splittings, spin-lattice relaxations, chromophore-matrix interactions, Herzberg-Teller/Franck-Condon activities, and localization/delocalization properties are treated.

Transition Metals in Coordination Environments

Transition Metals in Coordination Environments
  • Author : Ewa Broclawik,Tomasz Borowski,Mariusz Radoń
  • Publisher :Unknown
  • Release Date :2019-03-16
  • Total pages :532
  • ISBN : 9783030117146
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Summary : This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.

Spectroscopy in Inorganic Chemistry

Spectroscopy in Inorganic Chemistry
  • Author : C.N.R. Rao
  • Publisher :Unknown
  • Release Date :2012-12-02
  • Total pages :424
  • ISBN : 9780323150903
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Summary : Spectroscopy in Inorganic Chemistry, Volume I describes the innovations in various spectroscopic methods that are particularly effective in inorganic chemistry studies. This volume contains nine chapters; each chapter discusses a specific spectroscopic method, their fundamental principles, methods, instrumentation, advantages disadvantages, and application. Chapter 1 covers some of the general principles and experiments that have been used in the recording and interpretation of crystal spectra of molecules that contain transition-metal ions. Chapter 2 illustrates the application of spectroscopic techniques to the photochemistry of small inorganic molecules, non-transition-metal compounds, and transition-metal complexes. The remaining chapters examine several spectroscopic methods, such as matrix isolation, mass, soft X-ray, and Mössbauer spectroscopies, high-resolution NMR, and nuclear quadrupole resonance, with a particular emphasis on their effective application in inorganic chemistry studies. This book will be of great benefit to inorganic chemists, spectroscopists, and inorganic chemistry teachers and students.

Electronic Spectra of Transitions Metal Complexes

Electronic Spectra of Transitions Metal Complexes
  • Author : Vinod Jena
  • Publisher :Unknown
  • Release Date :2015-04-12
  • Total pages :91
  • ISBN : 9781329059870
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Summary : This books will provides a conceptual parts of Electronic spectra of various transition metal complexes, which is useful for various competitive examinations.

Spectroscopic Methods in Bioinorganic Chemistry

Spectroscopic Methods in Bioinorganic Chemistry
  • Author : Edward I. Solomon,Keith O. Hodgson,American Chemical Society. Division of Inorganic Chemistry
  • Publisher :Unknown
  • Release Date :1998
  • Total pages :468
  • ISBN : UOM:39015042167653
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Summary : This volume contains recent advances in spectrographic methods, including EPR, magnetic Mossbauer, paramagnetic and multi-D NMR, metalloprotein crystallography, EAS, magnetic circular dichroism, resonance Raman, X-ray absorption spectroscopy, and electron structure calculations. The book concentrates on topics where spectrographic methods have had a major impact, such as electron transfer, cluster interactions, intermediates, and definition of active site structure, and it includes a thorough tutorial on basic methods.

A Textbook of Inorganic Chemistry – Volume 1

A Textbook of Inorganic Chemistry – Volume 1
  • Author : Mandeep Dalal
  • Publisher :Unknown
  • Release Date :2017-01-01
  • Total pages :480
  • ISBN : 9788193872000
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Summary : An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Electronic Structure and Properties of Transition Metal Compounds

Electronic Structure and Properties of Transition Metal Compounds
  • Author : Isaac B. Bersuker
  • Publisher :Unknown
  • Release Date :2010-12-01
  • Total pages :759
  • ISBN : 9780470920855
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Summary : With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications. Including ~70 Example-Boxes and summary notes, questions, exercises, problem sets, and illustrations in each chapter, this publication is also suitable for use as a textbook for advanced undergraduate and graduate students. Novel material is introduced in description of multi-orbital chemical bonding, spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems. This is an excellent reference for chemists, researchers and teachers, and advanced undergraduate and graduate students in inorganic, coordination, and organometallic chemistry.

Analytical Chemistry of Macrocyclic and Supramolecular Compounds

Analytical Chemistry of Macrocyclic and Supramolecular Compounds
  • Author : Shripad Moreshwar Khopkar
  • Publisher :Unknown
  • Release Date :2005
  • Total pages :347
  • ISBN : 8173196818
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Summary : "This volume provides a comprehensive state-of-the-art account, exclusively devoted to the analytical chemistry of Macrocyclic (crown ethers), Macrobicyclic (cryptands) and the Supramolecular compounds (calixarene and calyx(n) resorcinarene and rotaxanes). These compounds having a great deal of similarity in their chemical characteristics have direct application in biosciences, analytical chemistry, solvent extraction, chromatography, spectroscopy and ion selective electrodes."--BOOK JACKET.

Molecular Electronic Structures of Transition Metal Complexes II

Molecular Electronic Structures of Transition Metal Complexes II
  • Author : David Michael P. Mingos,Peter Day,Jens Peder Dahl
  • Publisher :Unknown
  • Release Date :2012-01-11
  • Total pages :236
  • ISBN : 9783642273780
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Summary : T. Ziegler: A Chronicle About the Development of Electronic Structure Theories for Transition Metal Complexes.- J. Linderberg: Orbital Models and Electronic Structure Theory.- J.S. and J.E. Avery: Sturmians and Generalized Sturmians in Quantum Theory.- B.T Sutcliffe: Chemistry as a “Manifestation of Quantum Phenomena” and the Born–Oppenheimer Approximation?- A.J. McCaffery: From Ligand Field Theory to Molecular Collision Dynamics: A Common Thread of Angular Momentum.- M. Atanasov, D. Ganyushin, K. Sivalingam and F. Neese: A Modern First-Principles View on Ligand Field Theory Through the Eyes of Correlated Multireference Wavefunctions.- R.S. Berry and B.M. Smirnov: The Phase Rule: Beyond Myopia to Understanding.

Spectroscopic Methods in Organometallic Chemistry

Spectroscopic Methods in Organometallic Chemistry
  • Author : William O. George
  • Publisher :Unknown
  • Release Date :1970
  • Total pages :224
  • ISBN : UCAL:B4477494
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Summary :

Spectroscopic Analyses

Spectroscopic Analyses
  • Author : Eram Sharmin,Fahmina Zafar
  • Publisher :Unknown
  • Release Date :2017-12-06
  • Total pages :240
  • ISBN : 9789535136279
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Summary : The book presents developments and applications of these methods, such as NMR, mass, and others, including their applications in pharmaceutical and biomedical analyses. The book is divided into two sections. The first section covers spectroscopic methods, their applications, and their significance as characterization tools; the second section is dedicated to the applications of spectrophotometric methods in pharmaceutical and biomedical analyses. This book would be useful for students, scholars, and scientists engaged in synthesis, analyses, and applications of materials/polymers.

Molecular Electronic Structures of Transition Metal Complexes I

Molecular Electronic Structures of Transition Metal Complexes I
  • Author : David Michael P. Mingos,Peter Day,Jens Peder Dahl
  • Publisher :Unknown
  • Release Date :2012-01-11
  • Total pages :216
  • ISBN : 9783642273704
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Summary : J.P. Dahl: Carl Johan Ballhausen (1926–2010).- J.R. Winkler and H.B. Gray: Electronic Structures of Oxo-Metal Ions.- C.D. Flint: Early Days in Kemisk Laboratorium IV and Later Studies.- J.H. Palmer: Transition Metal Corrole Coordination Chemistry. A Review Focusing on Electronic Structural Studies.- W.C. Trogler: Chemical Sensing with Semiconducting Metal Phthalocyanines.- K.M. Lancaster: Biological Outer-Sphere Coordination.- R.K. Hocking and E.I. Solomon: Ligand Field and Molecular Orbital Theories of Transition Metal X-ray Absorption Edge Transitions.- K.B. Møller and N.E. Henriksen: Time-resolved X-ray diffraction: The dynamics of the chemical bond.

Spectroscopic Methods in Mineralogy and Geology

Spectroscopic Methods in Mineralogy and Geology
  • Author : Gordon E. Brown
  • Publisher :Unknown
  • Release Date :1988
  • Total pages :698
  • ISBN : UCSD:31822002411494
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Summary : Volume 18 of Reviews in Mineralogy provides a general introduction to the use of spectroscopic techniques in Earth Sciences. It gives an Introduction To Spectroscopic Methods and covers Infrared And Raman Spectroscopy; Inelastic Neutron Scattering;

Spectroscopic Methods in Organic Chemistry

Spectroscopic Methods in Organic Chemistry
  • Author : Dudley H. Williams,Ian Fleming
  • Publisher :Unknown
  • Release Date :1973
  • Total pages :244
  • ISBN : MINN:319510004695610
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Summary : Intended as a textbook suitable for a first course in the subject, and as a handbook for practising organic chemists.

Journal of Scientific and Industrial Research

Journal of Scientific and Industrial Research
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2005
  • Total pages :229
  • ISBN : UOM:39015039858553
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Summary :

Indian Journal of Chemistry

Indian Journal of Chemistry
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2008
  • Total pages :229
  • ISBN : CHI:80411787
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Summary :

Electronic Spectra of Transition Metal Complexes

Electronic Spectra of Transition Metal Complexes
  • Author : B.K.Kar
  • Publisher :Unknown
  • Release Date :2012
  • Total pages :514
  • ISBN : 8173815585
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Summary : The purpose of this book is to familiarize students with the concepts , methods and applications of crystal field theory as well as ligand field theory to a point where the literature on the subject can followed with much diificulty.

Mineral Chemistry; Research Report

Mineral Chemistry; Research Report
  • Author : Commonwealth Scientific and Industrial Research Organization (Australia). Division of Mineral Chemistry
  • Publisher :Unknown
  • Release Date :1967
  • Total pages :229
  • ISBN : UCAL:B3505572
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Summary :

Proceedings of the ... International Conference on Coordination Chemistry

Proceedings of the ... International Conference on Coordination Chemistry
  • Author : Anonim
  • Publisher :Unknown
  • Release Date :2021
  • Total pages :229
  • ISBN : CORNELL:31924056003829
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Summary :

Bulletin of the Chemical Society of Japan

Bulletin of the Chemical Society of Japan
  • Author : Nihon Kagakkai
  • Publisher :Unknown
  • Release Date :1995
  • Total pages :229
  • ISBN : STANFORD:36105009202479
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Summary :